Abstract

The phase equilibria of the systems SrO‐CuO and SrO‐1/2Bi2O3 were studied by X‐ray diffraction analysis of quenched powder samples. The compounds SrCuO2 and Sr2CuO3 melt incongruently at 1085° and 1225°C, respectively. The newly found compound Sr6Bi2O9 decomposes at 965°C into SrO and Sr3Bi2O6 melts incongruently into SrO and liquid at 1210°C. SrBi2O4 undergoes a phase transition at ∼825°C, and although both are nonstoichiometric, the low‐temperature phase is slightly poorer in SrO with 33.5 mol% SrO than the high‐temperature phase.

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