Abstract
The Flory lattice method has been utilized to study phase equilibria in solutions of disklike molecules. It is found that the critical disk diameter-to-width ratio x for the formation of the stable nematic phase is about 3.015. Temperature-concentration phase diagrams are studied for several values of x. For x8.6 isotropic and nematic phases are separated by a biphasic range of concentrations. Above x\ensuremath{\approxeq}8.6 a reentrant nematic feature appears, i.e., at a given temperature either of two pairs of phases, isotropic-nematic or nematic-nematic, occurred. The locations of the corresponding critical and triple points are computed. \textcopyright{} 1996 The American Physical Society.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.