Abstract
High pressure phase relation of the system Fe2SiO4–Fe3O4 was investigated by synthesis experiments using multi-anvil high pressure apparatus. A complete solid solution with spinel structure along Fe2SiO4–Fe3O4 join occurs above 9 GPa at 1200 °C. Lattice constants of the solid solution show almost linear variation with composition. A spinelloid phase is stable for intermediate compositions in the pressure range from 3 to 9 GPa. the synthesized spinelloid phase is successfully indexed assuming nickel aluminosilicate V type structure.
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