Abstract
In fluid (n-alkane + water) mixtures (gas + gas) equilibria of the second type are found. Phase equilibria in fluid (n-pentane + water) and (n-heptane + water) were measured in the temperature range 600 to 675 K and at pressures from 15 to 170 MPa. The critical curve of these systems starts at the critical point of pure water and runs through a temperature minimum with increasing pressure. Experimental results are compared with previous studies and it is found that the data fit very well within the systematics of other (n-alkane + water) systems.
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