Abstract

The Phase diagram of the pseudo-binary CrBFeB system was studied in the temperature range from 900 to 2200°C by using a piston-cylinder high pressure apparatus as a reaction vessel. The CrB-type phase was found to be unstable relative to the FeB-type phase at higher temperature. The magnetism and thermal expansion of the samples having the FeB-type structure were also studied in connection with their Invar properties.

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