Abstract
Discrete interfacially controlled condensation and addition reactions, including polymerization, are described in the case of conducting polymer film growth on salt crystals, as well as monolayer reactions on a water surface. It has been shown that the interface controls and limits the extent of reaction so as to minimize structural disruption of the film material. In virtually every case, the resulting polymer has a unique chemistry, structure, defect level or purity which cannot be obtained by any other method.
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