Abstract
Gas-liquid critical parameters of charged soft dumbbells (CSDs) as function of the site-to-site separation on the dumbbells, d, obtained on the basis of molecular dynamics computer simulation are presented. A mean field theoretical description is developed, which explains the results at small and large d, respectively. We note that in the limit d→0 the CSD system exhibits gas-liquid phase separation solely driven by repulsion and dipole-dipole interaction. If the dumbbell bond is eliminated the CSD system becomes similar to the restricted primitive model of ionic fluids with hard core repulsion replaced by soft repulsion. We obtain the gas-liquid critical parameters for this model and discuss their relation to the CSD system.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
