Abstract
The reaction of antimony chloride, sulfur and tetraphenylphosphonium bromide in an aqueous ammonia solution under hydrothermal conditions yields orange crystals of bis(tetraphenylphosphonium) μ-sufido-μ-tetrasulfido-S1:S4-bis[(pentasulfido-S1,S5)antimonate], [(C6H5)4P]2[Sb2S15]. The structure contains tricyclic molecular Sb2S152− anions built up of two distorted ψ-trigonal bipyramidally coordinated antimony centres which are connected by two Sx2− units (x = 1,4) and bound to an additional S52− ligand.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section C Crystal Structure Communications
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
