Abstract
A series of cross-linked, pH responsive vesicles with tunable diameters were prepared by self-assembly of poly (ethyleneoxide)-b-poly [2-(diethylamino) ethyl methacrylate-co-glycidyl methacrylate, ...
Highlights
Block copolymers can self-assemble into a variety of morphologies, both in solvent and in bulk [1,2,3,4,5,6,7,8,9,10]
The vesicles and micelles prepared from the self-assembly of amphiphilic block copolymers are widely used as drug loading and delivery vehicles and have attracted much attention in the past decade [11,12,13,14,15,16,17,18,19,20]
The development of intelligent vesicles responding to pH, temperature, redox and light became one of the most 2
Summary
Block copolymers can self-assemble into a variety of morphologies, both in solvent and in bulk [1,2,3,4,5,6,7,8,9,10]. The vesicles and micelles prepared from the self-assembly of amphiphilic block copolymers are widely used as drug loading and delivery vehicles and have attracted much attention in the past decade [11,12,13,14,15,16,17,18,19,20]. Based on the gelation reaction of poly(3-(trimethoxysilyl)propylmetha‐ crylate) (PTMPM), Du et al produced pH-responsive stable vesicles by incorporating pH-sensitive PDEA into the. Membrane was tuned by tuning the molar ratio of the diluted with DCM and passed through a column filled with neutral alumina to remove the CuBr. The block copolymer cross-linkable GMA unit and pH. The general procedure for the self-assembly of PEO45-bP(DEA-co-GMA) and cross-linking is as follows. Self-triggered cross-linking of P(DEA-co-GMA) at the vesicle’s membrane
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