Abstract

The present work deals with the study of proton - ligands and metal- ligands Constant of Binary and ternary complexes. Where M= Innertranition metals, L= Primary ligands( malic acid, ,maleic acid and Malonic acid) and secondary ligands B = Glycine have been studied Potentiometrically in biologically relevant conditions. At ionic strength μ= 0.1M NaClO4. All the ligands forns 1:1:1 ternary complexes, the relative stability of ternary complexes expressed in terms of statistical parameter Δ log k and - Δ log k values suggest that the formation of ternary complexes are favorable and variation of Δ log k has been explained in terms of metal-ligand-п interaction, size of chelate ring, and steric factor.

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