Abstract
We demonstrate that a tripodal hexaurea receptor can selectively bind PO43- anions via 12 hydrogen bonds with up to 3.8 × 106 M-1 binding affinity in DMSO, which is 38-fold stronger than SO42-. This receptor facilitates the extraction of PO43- from strongly basic aqueous solutions into chloroform using liquid-liquid extraction, followed by its release as the H2PO4- anion into an acidic solution. This pH-dependent phosphate extraction successfully enables selective separation of phosphate and sulfate anions.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
