Abstract

A series of Dy3+-doped Ga2O3 powders were prepared via a simple hydrothermal reaction method, conducted without the use of any surfactants at varying initial pH. X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Photo-Luminescence (PL), UV–Vis–NIR Diffuse Reflectance Spectroscopy (DRS), Electron Probe Micro-Analysis (EPMA) and WDS/EDS were employed to characterize the synthesized powders. The influence of starting solution pH on the growth process of the GaOOH particles and on the host-sensitized luminescence of the Dy3+:Ga2O3 powders were investigated in detail. It is revealed that the active energy transfer processes can be influenced by variation of the Dy3+ concentration, and that a starting solution pH value of 8 is optimal for maximizing Dy3+ incorporation into the Ga2O3 lattice. This work presents a method to produce Dy3+:Ga2O3 with tunable UV-pumped emission, and provides evidence that white emission can be achieved through careful control of dopant concentration, which makes the material attractive for solid state UV pumped-white emission applications.

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