Abstract
A configurationally-labile helical dye, 2,4,5,7-tetranitrofluorenone oximate, is used to probe complexes made of enantiopure macrocycles and mono/divalent metal ions. Induced electronic circular dichroism (ECD) and 1H NMR responses are amplified at room temperature only in the presence of K+ and Na+ ions despite larger binding efficiency with alkaline earth metal ions.
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