Petroleum heteroatom compounds in various commercial delayed coking liquids: characterized by FT-ICR MS and GC techniques

Abstract

Delayed coking is an important petroleum resid conversion process. The processability of coking liquids is known to be dependent on the heteroatom compounds present in the coking liquids. Eight commercial delayed coking liquids were characterized by electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) and gas chromatographic techniques. High relatively abundant heteroatom compounds in the coking liquids were 1–4 aromatic-ring pyridinic nitrogen compounds, carbazoles, benzocarbazoles, phenols, mercaptans, benzothiophenes, dibenzothiophenes, and naphthobenzothiophenes. Coking liquids derived from various feeds had similar compound class types, molecular weight distribution ranges, and double bond equivalents (DBE). However, the concentration of individual compounds and the distribution of DBE versus carbon number of heteroatom compounds varied. A comparison of heteroatom compounds in coker feeds and products revealed the various reaction mechanism of heteroatom compounds occurred during the coking process. The results suggested that molecular-level process models can be developed for optimization of unit operation to obtain desirable products that meet the environmental specifications and quality requirements.