Petrogenesis of Triassic granitoids in the Fengxian–Taibai ore cluster, Western Qinling Orogen, central China: Implications for tectonic evolution and polymetallic mineralization

Abstract

The petrogenesis and tectonic setting of the Triassic granitoids, and their relationship with the coeval Au and Pb–Zn polymetallic mineralization in the Western Qinling Orogen (WQO) in central China remain debated. The Fengxian–Taibai Ore Cluster (FTOC) in the eastern part of the WQO hosts large-scale Triassic granitoids and numerous polymetallic deposits, providing an excellent opportunity to constrain the controversies mentioned above. In this work, we choose the Huahongshuping granodiorite pluton, Guji biotite monzogranite pluton, Taoerling biotite monzogranite dike, Dongtangzi granite porphyry dike and Dagou dioritic dikes in the FTOC for a combined study on the zircon U–Pb geochronology, whole-rock major, trace elements and Sr–Nd isotopes. LA–ICP–MS zircon U–Pb dating yields ages of ~225 Ma, ~224 Ma and 227–217 Ma for the Huahongshuping pluton, Guji pluton and granitoid dikes, respectively. All these granitoids have metaluminous and high-K calc-alkaline series affinities, and are enriched in large ion lithophile elements (LILE), light rare earth elements (LREE) and depleted in high field-strength elements (HFSE) with a marked LREE/HREE fractionation ((La/Yb)N = 10.66–32.42), fractionation of LREE ((La/Sm)N = 2.72–6.60), and negative Eu anomalies (δEu = 0.45–0.99). They have initial Sr isotopic ratios of 0.7062–0.7082, and negative εNd(t) values of –9.42 to –8.09. The above features indicate that the FTOC granitoids were mainly derived from the partial melting of the Neoproterozoic meta-volcanic rocks induced by the decrease in pressure and the addition of water dehydrated from biotite, with direct contribution of mantle materials. Combined with previous data on sedimentation, deformation and metamorphism, and tectonics, we suggest that the WQO underwent the Early Mesozoic tectonic evolution from the subduction at 248–235 Ma, through syn-collision at 235–225 Ma, to post-collision at 225–195 Ma. Integrating with the ore geology, geochronology, mineralogy, and quartz and carbonate H–O, and in-situ S isotope data of sulfides from different mineralization stages at representative Au and Pb–Zn deposits in literatures, we propose a conceptive model that the post-collision process and granitic magmatic activity played an important role in the polymetallic mineralization within the FTOC.