Petrogenesis and Ni-Cu exploration potential of Devonian mafic–ultramafic intrusions in the southern part of the Central Asian Orogenic Belt, NW China: constraints from zircon O isotopes and whole-rock Sr-Nd isotopes

Abstract

ABSTRACT Weakly disseminated sulphide mineralization is present in the outcrops of several mafic–ultramafic intrusions in the Beishan region of the Central Asian Orogenic Belt in western China, but the potential of these intrusions to host economic sulphide ores at depths is not known. A better understanding of the genetic control on the mineralization may help to answer this important question. With this in mind, we have selected two of them that were emplaced during the Devonian, a period when subduction-related mafic magmatism undoubtedly occurred in the region, for a geochemical study. They are the Miaomiaojing and Guaishishan mafic–ultramafic intrusions. Our new zircon U-Pb dating indicates that they were emplaced at 377.5 ± 5.3 and 358.6 ± 3.9 Ma, respectively. Lherzolite, olivine websterite, troctolite and gabbro are the main rock types for both intrusions. Disseminated sulphide mineralization is concentrated in the ultramafic units of both intrusions. The whole-rock samples are characterized by light REE enrichments, pronounced negative Nb-Ta anomalies, and variable εNd(t) values from −3.54 to +2.17. Zircons from the intrusions have elevated δ18O values (average value: 7.48 ± 0.09 ‰) compared to that of the mantle. The trace element and isotope data support the interpretation that the parental magmas for the Devonian mafic–ultramafic intrusions are contaminated arc mafic magmas. Petrological modelling reveals that fractional crystallization together with crustal assimilation may have played an important role in triggering the sulphide saturation in the magmas. The Ni tenors (in recalculated 100% sulphide) for the sulphide-mineralized samples from both intrusions are similar and up to 6.7 wt% Ni and 2.8 wt% Cu, comparable to the metal tenor of most economic Ni-Cu deposits in the CAOB, implying that samples containing higher amounts of sulphides would become Ni-Cu ores. The olivine Fo and Ni contents from sulphide-bearing ultramafic rocks show a negative correlation, consistent with sub-solid Fe-Ni exchange between olivine and sulphide melt. Together with the similar mineralization characteristics between these sulphide-bearing intrusions and the coeval Heishan Ni-Cu deposit, we suggest that these intrusions have the potential to host Ni-Cu sulphide ores at depths, which could be further tested by geophysical survey followed by drilling.