Perturbative expansion of irreversible work in symmetric and asymmetric processes.

Abstract

The systematic expansion method of the solution of the Fokker-Planck equationis developed by generalizing the formulation proposed in [J. Phys. A: Math. Theor. 50, 325001 (2017)10.1088/1751-8121/aa7af4]. Using this method, we obtain an alternative formula to calculate the mean work perturbatively which is applicable to systems with degeneracy in the eigenvalues of the Fokker-Planck operator. This method enables us to study how the geometrical symmetry affects thermodynamic description of a Brownian particle. To illustrate the application of the derived theory, we consider the Fokker-Planck equationwith a two-dimensional harmonic potential. To investigate the effect of symmetry of the potential, we study thermodynamic properties in symmetric and asymmetric deformation processes of the potential: the rotational symmetry of the harmonic potential is held in the former, but it is broken in the latter. Optimized deformations in these processes are defined by minimizing mean work. Comparing these optimized processes, we find that the difference between the symmetric and asymmetric processes is maximized when the deformation time of the potential is given by a critical time which is characterized by the relaxation time of the Fokker-Planck equation. This critical time in the mean work is smaller than that of the change of the mean energy because of the hysteresis effect in the irreversible processes.