Abstract
A relatively simple treatment using perturbation theory is proposed to describe spectrum of pseudorotational states in cyclic-N(3). The purpose is to develop an analytical expression that could be used to fit the experimentally determined spectrum of cyclic-N(3), with purpose of identifying this molecule in the laboratory and deriving parameters of its potential energy surface directly from the experimental data. The perturbation theory expression derived in this work is used to fit the spectrum calculated numerically in the previous work [D. Babikov and B. Kendrick, J. Chem. Phys. 133, 174310 (2010)]. It is found that the second order of perturbation theory works well, giving a very good fit of the spectrum, with the rms deviation of only 0.26 cm(-1). Analysis reveals that important characteristics of the potential energy surface, such as equilibrium geometry and pseudorotation barriers, are directly related to the features of spectrum, such as splittings, and can be readily derived from experimental data, when those become available.
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