Perturbation induced by EDTA on HDO, Br- and EuIII diffusion in a large-scale clay rock sample

Abstract

Clay rocks are widely studied in the context of waste landfill leachates or as geological barriers for nuclear waste management. The release of organic co-contaminants by wastes may alter clay rocks, depending on the ratio between the volume of wastes and the mass of rock. In this work, a 10mM EDTA plume was injected in a large-scale clay rock sample with a low V/m ratio (<< 1.0Lkg-1) close to environmental conditions. The chemical perturbation was monitored for 450days, as well as its effect on HDO, Br-, and EuIII diffusion. Alteration of carbonates and iron-rich phases was evidenced in addition to the decrease of tracer concentration. Negatively charged complexes of EDTA and Eu are slightly adsorbed on minerals surface and display a desorption hysteresis. Transport parameters including diffusion anisotropy of HDO, Br, and EDTA complexes are estimated. Results are discussed with emphasis on determination of the mechanisms governing such a perturbation and the corresponding transitory state.