Abstract
In this work, Fe3O4/CoNi-MOF was synthesized by a simple solvothermal method. The catalytic performance of 0.2-Fe3O4/CoNi-MOF toward PMS activation was studied by degradation of 20mg/L methylene blue (MB). The results indicated that 0.2-Fe3O4/CoNi-MOF had good catalytic ability, the removal rate of MB was 99.4% within 60min with 125mg/L PMS and 150mg/L catalyst. Quenching experiment and electron paramagnetic resonance (EPR) analysis revealed that the singlet oxygen (1O2), superoxide radical (•O2-) and sulfate radical (SO4•-) played a crucial role in the catalytic degradation process. Meantime, mechanism of PMS activation by 0.2-Fe3O4/CoNi-MOF was proposed, the electrons donated by Fe2+ can also enhance the Co-Ni cycles. In conclusion, Fe3O4/CoNi-MOF composite catalyst has the advantages of simple preparation, excellent catalytic activity and reusability, which is an effective catalyst for water pollution control.
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