Peroxo Salts as Initiators of Vinyl Polymerization. 6. Kinetics of Polymerization of Acrylonitrile Initiated by Potassium Peroxodisulfate in Aqueous Medium-Ag+Catalysis

S P Manickam,N R Subbaratnam,K Venkatarao

doi:10.1080/00222338108056798

Peroxo Salts as Initiators of Vinyl Polymerization. 6. Kinetics of Polymerization of Acrylonitrile Initiated by Potassium Peroxodisulfate in Aqueous Medium-Ag+Catalysis

S P Manickam, N R Subbaratnam + Show 1 more

https://doi.org/10.1080/00222338108056798

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Journal: Journal of Macromolecular Science: Part A - Chemistry	Publication Date: Jun 1, 1981
Citations: 7

Affiliation: Madurai Kamaraj University, University of Madras

#Potassium Peroxodisulfate #Cata-lytic Effect Of Ag + Show 8 more

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Abstract

Abstract The kinetics of polymerization of acrylonitrile initiated by potassium peroxodisulfate in neutral and acid conditions was studied. Rp depended upon [S2O8 2-]1/2 and [monomer]3/2 both in neutral and acid solutions. The influence of ionic strength and the cata-lytic effect of Ag+ on the System are discussed. Suitable mech-anisms are proposed.

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