Abstract
The peroxo complexes of molybdenum and tungsten are reactive intermediates in catalytic oxidation of lots of organic substances. Some of the peroxo complexes of the platinum family metal complexes are known to react with inorganic molecules, such as: NO, NO2, SO2, CO and CO2 [1, 2]. In our investigations we used peroxo complexes of chromium (VI), molybdenum (VI) and tungsten (VI) for carrying oxygen atoms from water molecules onto small acceptors of biological importance i.e. nitric oxide and carbon oxide. The best results of these processes were obtained for [MO(O2)2(L)]2−, M = Mo, W and L = carboxylate ions: ox, glyc, tart, mal, cit and [M2O2(O2)4(tar/)]4−, M = Mo, W.
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