Permylene™ membrane technology: An efficient approach to separate propylene from propane

Abstract

Permylene™ demonstration system (PDS), a membrane-based pilot unit for olefin/paraffin separation, is designed and fabricated by Imtex Membranes Corp. (Imtex). The PDS, equipped with pilot-scale Permylene™ elements, is capable of treating up to 3 kg/h of olefin/paraffin mixture. The PDS unit is installed in Imtex's testing lab in Mississauga, Ontario, Canada. Various plant-collected and lab-blended olefin/paraffin mixtures involving ethylene/ethane (C2), propylene/propane (C3), and butene/butane (C4) have been assessed on the unit. This paper is focused on the application of PDS for C3 separation, and a series of remarkable performances that have been achieved by the Permylene™ membrane and PDS unit. Propylene purity of over 98.5 vol% in the permeate/product stream has been reached over a wide range of propylene recovery rates, which could offer significant flexibility to meet various industrial operation conditions. Furthermore, the PDS unit demonstrates its stability and efficiency with 1200 hrs of continuous C3 permeation. Finally, a case study of recovering 90 % of propylene from 15,000 kg/h of C3 is performed to estimate energy consumption in commercial applications. The energy consumption of the Permylene™ process is calculated and compared with that of the distillation process. The result indicates that the energy consumption in PDS is extremely low, equal to only 8 % of that required in distillation. The study undeniably validates Permylene™'s remarkable capability for C3 separation, highlighting its potential as a viable and energy-efficient alternative to traditional distillation.