Abstract
The matrix elements required for calculating the energy levels for a periodic potential function containing both sine and cosine terms are presented. Such potential functions are applicable for internal rotation when the top and/or the frame of the molecule belongs to the C 1 symmetry point group. The energy levels and wavefunctions are described for two characteristic potential functions—one with three different maxima and three different minima, the other with two different maxima and two different minima.
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