Periodic Heterogeneous Surface with Superhydrophilic/Superhydrophobic Stripes Processed by a Picosecond Laser.

Abstract

Heterogeneous surface with superhydrophilic/superhydrophobic stripes (HS-s/sS) has great practical significance, which can be used in fuel cell water management, condensation heat transfer enhancement, underwater drag reduction. Herein, a fast and simple method for uniform HS-s/sS on several mesh materials, including copper, stainless steel, and nickel, is achieved by using picosecond (ps) laser line-by-line scanning. Note that the scanning period between the lines is kept constant during processing, the HS-s/sS is formed by self-organized, while the similar structure cannot be processed on solid metal surfaces using the same parameters. The processing parameters, including scanning speed, defocus amount (DA), scanning period, and single pulse energy are systematically investigated to optimize HS-s/sS fabrication. It is found that the period of processed stripe on the mesh material is ∼1 mm, which is much larger than the scanning period. Interestingly, the as-prepared mesh surface show superhydrophobicity in the convex striped surface and superhydrophilicity in concave striped parts. The scanning electron microscopy results show that the structures on convex stripe are mainly composed of disordered hill-like structures, while the structures on the concave stripe mainly consist of periodic nanostripe structures. Moreover, the proportion of oxygen on the convex stripe is obviously higher than that on the concave stripe. The underlying mechanism of the HS-s/sS formation can be attributed to the interference between surface phonon polaritons (SPP) and the incident picosecond laser, as well as surface shock wave caused by the picosecond laser. We believe that such functional surfaces will be promising candidates for controlling liquid motion and fluid diversion processes.