Abstract

The formation of periodic arrays of intramolecular junctions in silicon nanowires from a single growth process is reported. Scanning tunneling microscopic images show intramolecular junctions formed by fusing together two straight wire segments (∼3 nm in diameter) 5 and 10 nm long, respectively, at an angle of ∼30° with respect to each other. The junction repeats itself in a regular pattern along a nanowire, forming a striking superlattice ∼3 nm in diameter and at least several microns long. Scanning tunneling spectroscopic measurements reveal distinctly different current–voltage curves for the two different segments changing sharply across each junction. The segments are most probably formed by a periodic change of growth direction while the different electronic properties of the two segments forming the junction are attributed to the differences in surface structure and segment diameter.

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