Abstract
A new symmetrical diseleno peri-bridged naphthalene, dinaphtho[1,8- b,c]-1,5-diselenocin ( 1), and 1,8-bis(methylseleno)naphthalene ( 2) have been synthesized. The cyclic voltammogram of 1 and 2 showed one reversible oxidation peak with remarkably low oxidation potential. Selenide 1 in CHCl 3 under air and scattered light undergoes oxidation to give the corresponding Se-oxide 11. The peri selenium-selenium interaction of 1 and 2 was found in electrochemical oxidation, in concentrated sulfuric acid, and in EI mass spectrum.
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