Abstract
Effective pretreatment of reverse osmosis (RO) influent is of great importance for reducing membrane fouling risks during coking wastewater desalination. In this study, the combined resin adsorption and ozonation pretreatment was investigated on alleviating RO membrane organic fouling. The performance of combined process was compared with only resin adsorption or ozonation, which was evaluated in terms of changes in chemical oxygen demand (COD), ultraviolet-visible index, and three-dimensional excitation-emission matrix fluorescence spectra. RO membrane fouling tests were conducted to examine the effects of pretreatment on flux decline and filtration resistance. The surface morphology and functional groups of membrane before and after fouling was characterized by scanning electron microscopy and infrared spectroscopy. The correlation between major organic matter in the wastewater and normalized RO membrane flux was established via multiple linear regression equations. The results showed that ozonation was more effective in removing COD and fluorescent organics than resin adsorption. Moreover, the combined bifunctional resin adsorption/ozonation unit showed the best performance, with COD and UV254 removal rates of 49.4 % and 88.0 %, respectively. The fluorescence intensity of each component decreased significantly. Meanwhile, the polysaccharide and protein components of the RO membrane fouling layer were effectively reduced by 67.2 % and 80.8 %, respectively. Most importantly, the combined pretreatment substantially reduced the decline in membrane flux and filtration resistance. Meanwhile, the fulvic acid-like organics in the wastewater showed high correlations with normalized membrane flux. The regression equation was beneficial for RO membrane fouling evaluation.
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