Performance of photocatalytic ozonation process for pentachlorophenol (PCP) removal in aqueous solution using graphene-TiO2 nanocomposite (UV/G-TiO2/O3).

Abstract

The aim of this study was to evaluate the efficiency of photocatalytic ozonation process using graphene-dioxide titanium nanocomposite in removing Pentachlorophenol (PCP) from aqueous solutions. In this study, nanocomposites with graphene to TiO2(G/T) ratios of 1:10 and 1:20 were synthesized by hydrothermal method, and its characteristics were assessed using various analyses, SEM, XRD, FTIR, TEM, BET and TGA. In this process, the effects of parameters including O3 concentration (0.25-1.25mg/L), nanocomposite concentration (50-500mg/L), initial PCP concentration (10-100mg/L), and time (10-60min), were studied. The results showed that PCP removal efficiency was increased by decreasing solute concentration. Increasing nanocomposite dose to 100mg/L was led to an increase in efficiency (99.1%), but then a decreasing trend was observed. Increasing the concentration of ozone, up to specific value, also enhanced the efficiency but then had a negative effect on process efficiency. Furthermore, the optimum ratio of the catalyst was determined to be 1:20. The highest efficiency of the process for initial pentachlorophenol concentration of 100mg/L was obtained 98.82% in optimum conditions (catalyst dose of 100mg/L and 60min). It is concluded that the photocatalytic ozonation process using graphene-dioxide titanium nanocomposite had the highest efficiency in removal and mineralization of PCP.