Performance of interstitial thermal barrier materials on containing sidewall rupture and thermal runaway propagation in a lithium-ion battery module

Abstract

Containing thermal runaway propagation in lithium-ion battery packs is a pertinent problem that is exacerbated when considering high energy density batteries and severe battery failure modes, such as sidewall rupture. This work investigates five different passive thermal barrier materials for their performance with respect to containing sidewall rupture and mitigating thermal runaway propagation between high energy density 21,700 cells. Along with propagation rate and total count of sidewall rupture failures, two new key performance indicators are introduced, the temperature reduction value and the sidewall rupture ratio, to quantify a material's performance. Overall, a stainless steel thermal barrier coated with an intumescent flame-retardant fabric performs best out of the five materials investigated. Evidence is given for the count of sidewall ruptures being linearly correlated to the propagation rate. It is shown that cells that fail with sidewall rupture have an average maximum surface temperature of 919 °C compared to 653 °C for cells that fail with top cap rupture. Evidence is also presented that sidewall rupture propagates to adjacent cells in a module. This work aims to provide battery pack designers with information to aid them in determining a strategy for containing thermal runaway propagation and sidewall rupture, including a method to evaluate the performance of thermal barrier materials against this objective.