Abstract
The increasingly restrictive legislation on the use of hazardous chemicals in lubricant formulation necessitates the use of less hazardous lubricant additives in the sheet metal forming industry. The tribological performance of calcium carbonate (CaCO3) as a green lubricant additive was evaluated in comparison to commercially available forming lubricants used in industry, some of which contain hazardous chemicals such as chlorinated paraffins to enable their function. The lubricants were tested by four-ball wear testing, four-ball weld load testing, and bending-under-tension. The ease of cleaning of surfaces formed with the different lubricants was evaluated by methods used in industry and the viscosity was evaluated using standard methods. The CaCO3 mixtures showed a better performance than commercial lubricants in four-ball wear testing, worse performance in four-ball weld load testing, worse cleanability, and a similar development of drawing force in bending-under-tension over 1000 consecutive strokes. When added to fully formed commercial lubricants, the particles degrade the performance of the lubricant in resisting adhesive wear but improve its capacity for resisting abrasive wear. Surfaces of formed parts after bending-under-tension testing with CaCO3 mixtures were scratched, while parts formed using commercial lubricants showed less scratching. The effect of including particles in a commercial lubricant depended on the application, either degrading it or improving it. It is therefore clear that the use of solid particles as lubricant additives should be constrained to selected applications where abrasive wear is a dominant wear mechanism.
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