Performance of high temperature phase-stable high entropy oxide (MgCuMnCoFe)Ox in catalytic wet air oxidation of chloroquine phosphate

Abstract

With the continuous spread of COVID-19, the water pollution problems caused by the abuse of chloroquine phosphate (CQP) as an antiviral drug have attracted wide attention. The cubic Fm-3m spinel high entropy oxide (HEO)—(MgCuMnCoFe)Ox was prepared by coprecipitation method as the catalytic wet air oxidation (CWAO) catalyst to treat CQP simulated wastewater. Through electron spin resonance (ESR) analysis, HEO will stimulate the production of superoxide radical (·O2−) and hydroxyl radical (·OH) in the wet air oxidation (WAO) process, which accelerates the degradation and mineralization of CQP. Through response surface method (RSM) optimization, the optimal degradation conditions of CQP in CWAO were proposed: initial oxygen pressure of 15 bar, catalyst dosage of 1.4 g/L and temperature of 230 °C. The advantages of HEO in CWAO were analyzed by principal component analysis (PCA). The degradation mechanism of CQP in CWAO by (MgCuMnCoFe)Ox were explored. This work provides a new idea for the rapid development of HEO in the field of environmental catalysis.Supplementary InformationThe online version contains supplementary material available at 10.1007/s10853-022-07271-z.