Performance of electronic waste based mixed metal oxide as novel oxygen carriers for chemical looping co-combustion of high ash coal and rice straw.

Abstract

Electronic waste (e-waste) is one of the major pollutants accumulated due to its huge demand and short lifespan. Hence, it is essential to reuse and extract the value added components from e-waste. In this context, firstly, a printed circuit board (PCB) is used to produce calorific valuable gases by pyrolysis and gasification reactions. Secondly, the resultant residue of PCB is combusted to extract metals such as iron, copper, nickel etc. as oxygen carriers for the chemical looping combustion (CLC) process. CLC is an emerging and appealing technology for producing rich CO2 that can be directly sent for sequestration. In the present study, a detailed investigation is performed to ensure the reactivity of the e-waste based metal oxide with high ash coal, rice straw and their blends in the CLC process. CO2 yield, gas conversion, and char conversion are evaluated to assess the performance of the co-combustion based CLC process. It is found that 90.9% CO2 yield, 94.1% gas conversion and 93.2% char conversion can be obtained using the blends of coal and rice straw in the first cycle of the CLC operation. Further, a reduction of 5% to 7% of these parameters is evaluated at the end of the third consecutive cycle of CLC operations. The interaction between coal and rice straw is further studied by evaluating their synergistic effects, char-oxygen carrier interaction and kinetic parameters using a thermogravimetric analyzer under N2 and CO2 atmosphere. The co-combustion process has reduced the activation energy by 13.4% at 800-1000°C under CO2 atmosphere.