Performance of a novel dot matrix fuel cell using an inorganic micro‐proton conductor

Abstract

AbstractThe power generation properties of a novel dot matrix fuel cell using an inorganic micro‐proton conductor were evaluated in dry gas mixtures of hydrogen and oxygen during room‐temperature operation. The single dot matrix fuel cell was composed of aggregates of micro‐electrolyte dots filling pores arranged in a matrix form on a Teflon or polyimide substrate with Pt/C and Pt catalytic electrodes. Micro‐electrolyte dots were prepared by the sol–gel method using titanium phosphorus oxides as the proton conductive hybrid materials. The open‐circuit voltage of the single cell became higher when using a small dot diameter and achieved a maximum of 500 mV with an electrolyte dot density of 17 dots/cm2 in the dry gas mixtures during room‐temperature operation. This value corresponds to about one‐half of the theoretical electromotive force. Moreover, the current density of the single cell increased with the dot diameter such that it grew to 8 mA/cm2 at a dot diameter of 500 µm. As a result, dot matrix fuel cells connected in series and parallel were found to achieve the cell performance of high‐energy density such as used by high‐energy microchips. © 2012 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.