Abstract

AbstractTo prepare inorganic nanoparticles filled polymer composites, reactive monomer was added to the ingredients prior to manufacturing. The results showed that in-situ graft polymerization of butyl acrylate onto nano-silica occurred during melt compounding with polypropylene matrix. As a result, dispersion of the grafted nanoparticles in the polymer became much more homogeneous than in the case of untreated version, and filler/matrix interaction was enhanced due to the intimate adhesion among the components. Both tensile performance and impact toughness of the composites were improved at rather low filler loading. Compared to the twostep approach developed in our lab, by which nanoparticles are treated by graft polymerization firstly and then mixed with polymer melt, the current one-step method is simpler and able to provide the composites with much higher notched impact resistance.

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