Abstract

The dosimetric response of silicon diodes produced with distinct engineering technologies, Magnetic Czochralski (MCz), and standard Float Zone (Fz), has been investigated, aiming at their use for online dosimeters in gamma radiation processing applications. The p+-n-n+ junction diodes, 300 µm thick with an active area of 25 mm2, are operated as online radiation dosimeters in the short-circuit current mode. In this case, the key dosimetric quantity is the dose rate, which is correlated with the output current from the diode subjected to radiation. Thus, the dose is obtained offline by the integration of the corresponding current signal. The irradiations are performed with an industrial Gammacell 60Co facility at 2.3–2.44 kGy/h covering doses up to 275 kGy. Under continuous irradiation, both diodes delivered current signals whose intensities decreased with accumulated doses. Mitigation of this decay has been accomplished by pre-irradiating the devices to 700 kGy. Polynomial functions best represent the dose responses for either pristine or preirradiated diodes. The relevant dosimetric parameters as response stability, charge sensitivity, and repeatability of current signals (<5%) reveal the better performance of the MCz diode. It is important to note that the whole dataset fully complies with the international standard protocols for routine dosimeters in radiation processing dosimetry. Regarding radiation damage, which in unbiased diodes manifests primarily in the decay of current sensitivity, the results also showed greater tolerance of the MCz diode. Based on these studies, large availability, and better cost-effectiveness, it is possible to endorse the potential use of MCz devices as online routine dosimeters in radiation processing applications. However, the data reproducibility with the accumulated dose, the dose lifespan, and the effect of the irradiation conditions (e.g., temperature, relative humidity, and dose fractionating) remain to be investigated. Works in this direction are currently in progress.

Highlights

  • Radiation processing is a growing industry where electrons, gamma, and X-rays irradiate products to improve their characteristics by tightly controlling the delivered absorbed doses

  • At the beginning of the irradiation, due to the higher purity level of the Float Zone (Fz) diode, its output current is higher than that delivered by the Magnetic Czochralski (MCz) diode

  • The dosimetric response of two types of silicon diodes produced with distinct engineering technologies, Magnetic Czochralski (MCz) and standard Float Zone (Fz), have been investigated, aiming their application to gamma radiation processing dosimetry

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Summary

Introduction

Radiation processing is a growing industry where electrons, gamma, and X-rays irradiate products to improve their characteristics by tightly controlling the delivered absorbed doses. The main radiation processing applications are the modifications of polymers, treatment of foodstuffs, and sterilization of medical devices, which encompasses high dose rates (up to tens of kGy/s) and absorbed doses (10–100 kGy) (Mclaughlin and Desrosiers, 1995). Several wellestablished high dose dosimetry systems, such as calorimeters, alanine, and polymers (polymethyl methacrylate, cellulose triacetate, radiochromic films) meet most of these requirements, being suitable for absolute and relative dose measurements at gamma and electron beam facilities (ISO/ ASTM 52628, 2013; ISO/ASTM 51649, 2015). All these dosimeters are passive, i.e., the dosimetric parameter readout is performed after the irradiation ends, not allowing the irradiation processes to be continuously monitored. The main motivation for monitoring industrial irradiation processes with real-time dosimeters stems from their capability of prompt dose assessment of the irradiated product, allowing for action-on-spot when needed and avoiding increases in production costs

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