Performance and microstructure development of lime – calcined fluvial sediment binders under different curing conditions

Abstract

Fluvial sediments need to be periodically dredged from waterways. At the same time, the building sector has to find high-volume alternatives to the extraction of non-renewable mineral resources. In this context, recent research has shown the benefit of reusing calcined sediments as supplementary cementitious materials. On a different note, this study examines the hydration and performance of blends of calcined fluvial sediment with low amounts (10 to 30 wt%) of hydrated lime with the aim of keeping the carbon footprint of the binder the lowest as possible. The effect of different curing conditions (moist curing at 20 °C or 50 °C and dry curing at 65%RH) is studied on compressive strength, reaction kinetics (fixed lime by TGA and heat of hydration), reaction products (XRD), microstructure (SEM) and porosity (MIP). The outcomes of the study revealed that heat curing for 3 days and 10 wt% of lime results in satisfactory strength development for the design of bio-based concretes (compressive strength of 9 MPa). Furthermore, the highest compressive strength of 17.5 MPa was achieved at 110 days at 20 °C for the mix with 20 wt% of lime. The amount of unreacted lime was found to be the highest for the mix including 30 wt% of lime for which the degree of reaction of lime at 90 days was around 0.7 for both curing temperatures. Under dry curing, a large part of the initially available lime was carbonated and some reaction products underwent carbonation leading to very low strength by 110 days.