Performance and mechanisms of fly ash for graphene oxide removal from aqueous solution.

Abstract

The potential wide use of graphene oxide in various fields results in the possibility of its dispersion throughout natural water systems, with a negative impact on organisms and ecosystems. This study evaluated the removal of graphene oxide (GO) from water by fly ash (FA). The effects of various conditions (including the initial concentration of graphene oxide, the pH of the initial solution, the amount of absorbent, and temperature) on the removal rate of GO were investigated in detail. The results show that the maximum removal rate of graphene oxide by fly ash is 93%; the isotherm adsorption process conforms to a Langmuir model; the adsorption reaction is a spontaneous exothermic process. Under optimal conditions, the pH of the solution was adjusted to 6, the amount of fly ash was 5 mg, the initial concentration of GO was 60 mg·L-1, and the temperature was 303 K. Using X-ray diffraction (XRD), Raman spectroscopy (Raman), Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), transmission electron microscopy (TEM), Zeta potential and X-ray electron spectroscopy (XPS), the adsorption mechanism was characterized. The experimental results demonstrate that fly ash is a good material for GO removal from aqueous solution.