Perfluoroalkyl-philic Character of Poly(2-hydroxyethyl vinyl ether)-block-poly[2-(2,2,2-trifluoroethoxy)ethyl vinyl ether] Micelles in Water: Selective Solubilization of Perfluorinated Compounds

Abstract

Two types of amphiphilic block copolymer, poly(2-hydroxyethyl vinyl ether)-block-poly[2-(2,2,2-trifluoroethoxy)ethyl vinyl ether] (poly(HOVE-b-TFEOVE)) (m:n = 78:23) and poly(2-hydroxyethyl vinyl ether)-block-poly(n-butyl vinyl ether) (poly(HOVE-b-NBVE)) (m:n = 74:23), having the same ratios of polymerization degree in hydrophilic and hydrophobic segments with the same total chain length were synthesized, and the properties of their aqueous solutions were investigated, where m and n represent number-averaged polymerization degree of HOVE and TFEOVE or NBVE, respectively. By water surface tension measurements, the critical micelle concentrations (cmc's) of poly(HOVE-b-TFEOVE) and poly(HOVE-b-NBVE) were both estimated at 1.0 × 10-4 mol/L. Solubilization of various fluoro and non-fluoro compounds using these polymer aqueous solutions was examined. It was confirmed that poly(HOVE-b-TFEOVE) solubilized more decafluorobiphenyl than did poly(HOVE-b-NBVE), whereas poly(HOVE-b-NBVE) solubilized more 2,6-dimethylna...