Perfluoro(7-methylbicyclo[4.3.0]nonane) and Perfluoro(butylcyclohexane): Physicochemical, Thermophysical, and Spectral Data

Abstract

New physicochemical data for perfluoro(7-methylbicyclo[4.3.0]nonane) and perfluoro(butylcyclohexane) with a purity ≥ 0.991 mass fraction are presented: the temperature and heat of the solid–liquid phase transition, the dependence of saturated vapor pressure, viscosity, density (liquid molar volume), and refractive index on temperature; the coefficients of the Antoine equation; 19F and 13C NMR and FTIR spectra; and gas chromatography–mass spectrometry data. For the perfluoro(7-methylbicyclo[4.3.0]nonane)–perfluoro(butylcyclohexane) binary system, the dependences are given: refractive index (at 15 °C) and density (at 20 °C) on the composition and boiling point on the composition in the pressure range from 20 kPa to atmospheric pressure. The average integral value of the relative volatility coefficient for various concentration ranges at atmospheric pressure is determined.