Perchloroethylene (PCE) adsorption on coal macerals as derived from micro-FTIR spectroscopic analysis and mapping of the C=C bonds from PCE

Abstract

ABSTRACT Organic liquids are used to prepare the density medium to produce clean coal composites for coal quality and coking test evaluations during the coal exploration stage. Perchloroethylene (PCE) is commonly used as a density medium for this procedure; however, it has been shown before that PCE affects Gieseler Fluidity and Ruhr Dilatation indices of coal, as well as the quality of the resulting coke. It was also found that PCE has a negative effect on the coking properties of coals with a high inertinite content. This paper investigates the adsorption of PCE on various coal maceral surfaces using micro-Fourier Transform Infrared Spectroscopy (micro-FTIR) analysis to observe the changes in the absorbance of the double carbon bond C = C (C = C absorbance peak is used as a marker to indicate the presence of PCE) before and after PCE was applied onto their surfaces. The micro-FTIR mapping of absorbance intensity of the C = C bond on coal macerals showed an increasing trend in the presence of these bonds on the surface of all macerals with the time after exposure to the PCE. The SEM- energy-dispersive X-ray spectroscopy was used to analyze the composition of minerals associated with fusinite and semifusinite, as they were filling the pores in these macerals.