Year-end Sale % OFF 
Abstract
Attempted preparation of neutral hexacoordinate silicon chelates with two O→Si dative bonds (4), in analogy to previously reported bis-N→Si isomers (2), resulted in unexpected formation of pentacoordinate siliconium complexes (5 and 6), characterized by a crystal structure. The barrier for inversion of configuration at silicon was determined by selective inversion recovery NMR measurements: ΔG* = 20.5 ± 0.2 kcal mol-1.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
