Abstract

In the title compound, [Zn(CH3CN)(H2O)5](C6H4O8S2)·3H2O, the ZnII ion lies on a mirror plane and is octa­hedrally coordinated by one acetonitrile ligand and five water mol­ecules. The 4,6-dihydroxy­benzene-1,3-disulfonate anion, acting as a counter-ion, is also located on the mirror plane. The crystal packing is stabilized by O—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network.

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