Penta- and hexacoordinate antimony(V) compounds with the tridentate O,N,O-donor ligand: Electrochemical transformations and antiradical activity

Abstract

The electrochemical transformations and antiradical activity of penta- and hexacoordinate antimony(V) complexes I–V containing the tridentate O,N,O-donor ligand, N,N-bis(di-3,5-tert-butyl-2-hydroxyphenyl)amine, are studied. The oxidation of hexacoordinate triarylantimony(V) compounds R3Sb(Cat-NH-Cat) (I–III) leads to the formation of neutral paramagnetic intermediates Ia–IIIa. Two anodic reversible one-electron stages are observed for pentacoordinate complexes R′2Sb(Cat-N-Cat) (IV, V). The possibility of the formation of stable paramagnetic species in electrochemical oxidation is a reason for the antiradical activity of the complexes. The study of the reactions of compounds I–V with the electrogenerated superoxide radical anion, diphenylpicrylhydrazyl radical, peroxy radicals, and hydroperoxides formed by the autooxidation of unsaturated fatty acids (oleic, linoleic) shows that all complexes exhibit a pronounced antiradical activity. The highest effect is observed for compounds I, IV, and V characterized by the prolonged action.