Abstract
The synthesis of unsymmetrical biaryls with a methylthio group is achieved using the air‐stable palladium–phosphinous acid complexes, [(t‐Bu)2P(OH)]2 PdCl2 (POPd), as the catalyst. A great variety of substituted bromobenzenes having electron‐withdrawing and electron‐donating functional groups in para and meta positions have been successfully coupled with 3‐methylthiophenylboronic acid.
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