Abstract
develop-ment of an efficient and general method for the introduction of carbon nucleophile at the primary position of Baylis-Hillman adduct is still highly required, especially in a stereoselective manner. Thus we decided to examine the cross-coupling reactions between the bromide of Baylis-Hillman adduct and allyl-, aryl-, and vinylstannane (Scheme 1) as a continuous work on our recent Pd-mediated reactions with Baylis-Hillman adducts.
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