Abstract
[Pd(IPr*OMe)(cin)(Cl)] provides high catalytic activity for Buchwald–Hartwig cross-coupling reactions of sterically demanding aryl chlorides with sterically hindered and deactivated aniline derivatives. This catalyst also proved efficient in Suzuki–Miyaura reactions, thus allowing the preparation of tetra-ortho-substituted biaryls. The Kumada–Corriu coupling has also been investigated using this palladium N-heterocyclic carbene (NHC) catalyst.
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