Abstract
A simple synthetic strategy of polyamide was described from melamine and terephalic acid via one‐step polycondensation. PdCl2 was then immobilized on the polyamide (denoted as Pd/MPA). Melamine and terephalic acid not only acted as monomers but also provided the ligand sites to help the polyamide to coordinate with Pd(II). The Pd/MPA catalyst was characterized by FT‐IR, TGA, SEM, TEM, XPS, N2 adsorption‐desorption and atomic absorption spectroscopy. The catalyst was used in Suzuki‐Miyaura coupling reaction of various aryl halides, including less reactive chlorobenzene and benzyl chloride, to give the coupling products in moderate to excellent yields. High turnover frequencies (TOF) up to 29400 h‐1 can be also obtained. In addition, it behaved truly as a heterogeneous catalyst with high reusability after being recycled 6 times and palladium leaching was negligible during the process. This work provides a practical polyamide support to develop heterogeneous palladium catalysts with simple synthetic procedure and low cost.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
