Abstract
Pd/HZSM-5 coating was prepared on the inner wall of φ3 tubular reactor by gas-aided fluid displacement and electroless plating technologies. The coating was characterized by means of SEM, XRD, and XPS. The coating surface was flat without flaws, with thickness of 12–16 μm and catalyst particle of size 1–5 μm. Metallic Pd particles were uniformly dispersed on the coating surface. The coating was used as the catalyst for the supercritical cracking of n-dodecane, a typical model compound of endothermic fuel. With the temperature of 640°C, pressure of 4 MPa, and resident time of 10 s, Pd/HZSM-5 showed very high cracking ratio of 55.5%, hydrogen yield of 3.1%, and heat sink of 3470 kJ/kg, which were increased by 8.5%, 58.7%, and 10.5% compared with HZSM-5 coating, respectively. Furthermore, they were 17.3%, 78.1%, and 13.5% higher than the case of thermal cracking reaction, respectively.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
