Pd catalyst supported on activated carbon honeycomb monolith for CO oxidation and the application in air purification of vehicular tunnel

Abstract

Different pretreatments (wet, oxidation and complex pretreatments) were used to modify activated carbon honeycomb monolith, and the role of surface properties of support in CO oxidation over Pd/ACHM catalysts was also investigated. Pretreatment was an efficient way to introduce oxygen groups, especially by complex pretreatment. Oxygen-containing groups increased 1.7 times as much as that of original ACHM, and 86% conversion was obtained at 30°C and 100% relative humidity on supported Pd catalyst prepared from modified ACHM. Oxygen-containing species on the support not only improved Pd dispersion but also affected Pd states. Compared with Pd dispersion, Pd states played a more important role in CO oxidation. The amount of low-valent Pd species (Pd0, Pd+1) on catalyst surface was consistent with CO oxidation activity. The presence of NO caused CO oxidation conversion to decrease by 15% which was attributed to the difference between NO and CO adsorption energy on Pd surfaces confirmed by density functional theory calculation. 90days' 1000m3/h pilot experiment results showed that the catalyst exhibited high activity and stability in the presence of moisture and NOx.